CDAC

Atoms are commonly thought of as being round.  New experiments by a CDAC-funded team from UC Berkeley and Northwestern University, together with scientists atand Argonne National Laboratory, report that pressure causes iron atoms to change shape deep inside our planet, however. This shapeshift alters the physical and chemical properties of crystals at depth, influencing the way Earth has evolved over its multi-billion-year history.

The high pressures of Earth’s interior can be reproduced in laboratory experiments that squeeze minerals samples between the tips of two diamonds. Previous experiments have shown that the electron clouds making up iron atoms within minerals collapse under less than a million times atmospheric pressure, conditions at roughly one quarter the depth toward our planet’s center. Dubbed an electronic spin transition, the change affects the electrons involved in chemical bonding between iron and other atoms, as well as the shape of the atoms.

This change in shape of the iron atoms has now been directly imaged for the first time at high-pressure, using high-intensity x rays from the Advanced Photon Source at Argonne National Laboratory. In their collapsed form, the iron atoms look like cubes with the corners cut off, and this affects how light, heat, and sound are transmitted through crystals containing iron.

Seismic waves from distant earthquakes are used to illuminate Earth’s interior, just as ultrasound is used for imaging the human body in medicine. High-pressure laboratory measurements are crucial for interpreting these seismic images and understanding the processes by which the interior cools over geological time.

Beyond imaging the shapes of atoms, the new measurements provide direct tests – means for improvements – of modern quantum simulations because the distribution of electrons within crystals is among the prime results obtained from atomistic theory. Quantum theory is widely used to develop new materials for society.

Atomic imaging at deep-Earth pressures is now a reality that can be used in basic science as well as applied technology.

The work was led by CDAC-funded graduate student, Matthew Diamond – now a postdoc at University of Illinois Chicago – as part of his Ph.D. thesis at UC Berkeley. This study has been published by M. R. Diamond, G. Shen, D. Y. Popov, C. Park, S. D. Jacobsen, and R. Jeanloz, Electron Density Changes across the Pressure-Induced Iron Spin Transition, href=”https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.129.025701″>Phys. Rev. Lett. 129, 025701 (2022).

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Studies of high-pressure material behavior  typically need to strike a balance between accessing the most extreme conditions and precise control of conditions, a choice that often limitsl the ability to investigate how materials deform when sheared and to find new materials with useful applications. A new study led by CDAC Academic Partner Susannah Dorfman at Michigan State University demonstrates a method for tuning the degree to which a sample is subjected to shear stresses while under simultaneous applied pressure.

The method is based on using a two-layered sample, similar to the bimetallic strip in a mechanical thermostat. When the two attached layers have different physical properties, they will expand or contract to different degrees when the temperature changes, causing the layers to bend together. A thin film (up to several hundred nanometers thick) sample in contact with a thicker substrate can curve enough to result in gigapascals of stress.

In a previous published work [Journal of Applied Physics 125, 245904 (2019)] graduate student Eric Straley in Dr. Jason Nicholas’ lab at MSU made thin film bilayers using pulsed laser deposition. Results from this work showed that the stress in the film determined by fluorescence spectroscopy was consistent with independent measurement of bending stress, and that a ruby film on a cubic zirconia substrate with contrasting physical properties retains ~1 GPa stress at standard temperature and pressure.

The new study combines these thin film bilayers with the diamond anvil cell, which can generate the highest static stresses possible in a laboratory setting. Again leveraging the strong fluorescence of ruby that is responsible for its characteristic red color, the variation in stress in the thin ruby film is measured as a function of additional confining stress. Measured stresses in a ruby film on a cubic zirconia substrate under compression (Fig. 1) continued to be significantly higher than a ruby on sapphire control sample due to bending of the bilayer. Differences in compressibility between the two layers also generated increasing amounts of bending stress in the sample, reaching as much as ~4 GPa when the confining pressure was 10 GPa.

The thin film combined with the diamond anvil cell method retains the advantages of the diamond anvil cell technique, including optical access to measurements and potential to reach hundreds of GPa pressures (millions of atmospheres), applicable to planetary cores and large explosive impacts. Future work using different materials may continue to tune stresses and useful properties in thin films over a wide range of conditions.

Co-author and former CDAC graduate student Ben Brugman is now a postdoctoral researcher at Arizona State University; Mingda Lv is now a postdoctoral researcher at HPCAT, and Samantha Theuer and Bella Arroyo were undergraduate participants in Professor Dorfman’s laboratory when this work was carried out.

S. M. Dorfman, S. Najiba, B. Arroyo, S. Theuer, M. Lv and B. L. Brugman, Control of deviatoric stress in the diamond anvil cell through thermal expansion mismatch in thin films. Physics and Chemistry of Minerals 49, 16 (2022).

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Electrochemical potential and applied pressure have each been used extensively to prepare new materials, such as pure aluminum (electrochemistry) and synthetic diamond (applied pressure).  However, these two fundamentally important approaches to chemical synthesis have not been combined, in part due to the difficulties of designing an apparatus that will perform electrochemistry inside a diamond anvil cell.  If the associated technical challenges could be overcome, the combination of electrochemistry and pressure (Fig. 1) could provide a powerful new method for the exploration of composition space in the effort to design new materials with tailored properties.

Recent evidence for room-temperature and even “hot” superconductivity in high-pressure hydrides beyond binary compositions suggests that increasing chemical complexity is a key requirement for increasing the superconducting critical temperature (T_c) for these materials. Static pressures near 200 GPa are required to stabilize superconducting superhydrides, and this is currently only achievable using the diamond anvil cell. More importantly, it is often the case that a complex superhydride decomposes into constituent simpler superhydrides even at such high pressures. Many complex superhydrides therefore may never achieve thermodynamic stability by  pressure alone, thus preventing thorough investigation of their interesting and important properties.

Following previous work that demonstrated the concept of combing pressure and electrochemistry to synthesize binary superhydrides, a new theoretical study carried out in a collaboration between researchers from Carnegie-Mellon University, Jilin University and the University of Illinois Chicago has recently extended this concept to a ternary hydride system, Li-Mg-H, where Li₂MgH₁₆ was previously calculated to have a superconducting critical temperature of ~ 470 K at 250 GPa. However, this complex phase is thermodynamically unstable against binary hydrides.

Combing first-principles calculations, crystal structure prediction and computational thermodynamics, phase diagrams of the Li-Mg-H system can be mapped over the space of composition, pressure and electrochemical conditions (electrode potential and pH), with the one at a fixed Mg/Li ratio between 0 and 0.25.  Two ternary Li-Mg superhydrides, Li₂MgH₁₆ and Li₄MgH₂₄ can be thermodynamically stabilized at suitable negative electrode potentials, if the hydrogen evolution reaction (HER) can be kinetically suppressed, which may be achieved by superconcentrated electrolytes or other mechanisms. The ground state of Li₂MgH₁₆ undergoes two polymorphic phase transitions at 33 and 160 GPa. The highest pressure phase is superconducting, while the two lower pressure phases are not.

This work shows the great potential of combing pressure and electrochemistry to synthesize novel multi-component superhydrides at low pressures, which may not be achieved even by applying multimegabar pressure alone. In practice, the highest achievable hydrogenation will depend on suppressing HER and on engineering issues like maintaining structural integrity of the highly hydrogenated electrode. Such a vast space of novel phases will provide many exciting opportunities for experimental and further theoretical research.

Guan, P.-W., Y. Sun, R. J. Hemley, H. Liu, Y. Ma, and V. Viswanathan, Low-pressure electrochemical synthesis of complex high-pressure superconducting superhydrides. Physical Review Letters 128, 186001 (2022).

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CDAC Academic Partner Eva Zurek, Professor of Chemistry at the University at Buffalo, has been elected to the chair line of the American Physical Society’s Division of Computational Physics.  Over the next four years, Professor Zurek will serve as Vice Chair, Chair-Elect, Chair, and Past Chair.

The goals of the Computational Physics Division are to “promote research and development in computational physics, enhance the prestige and professional standing of its members, encourage scholarly publication, and promote international cooperation in these activities.”

For more on Professor Zurek’s work, visit her research site.

Congratulations, Eva!

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The SSAP Symposium for 2022  was held virtually for the second year in a row on February 15-17.  The keynote address was given by Dr. Njema Frazier, who is the Assistant Deputy Administrator for Strategic Partnerships at DOE/NNSA.  Dr. Frazier outlined the changes taking place in the NNSA organizational structure that have been implemented in response to the strategic priorities articulated by the new administration.

Overview presentations were provided by all SSAP Grant Holders and Center Directors in the High Energy Density Laser Plasma, National Laser User Facility, Low Energy Nuclear Science, Radiochemistry and Materials Sections.  Russell Hemley provided updates CDAC scientific progress and student training activities since the Center’s move to the new host institution, the University of Illinois Chicago.

Breakout sessions held by representatives of the NNSA laboraotories gave students an opportunity to ask questions about postdoctoral research and staff positions, as well as the mission and research culture at each laboratory.

CDAC graduate students presented their research in the poster session.  Hannah Bausch, a graduate student in the group of Academic Partner Steven Jacobson at Northwestern University, received a Best Poster Award for her presentation, Shock-Ramp Compression of (Mg,Fe)O on the Z Machine: Preliminary Theory and Application to Ultra-Low Velocity Zones Atop the Core-Mantle Boundary. Hannah’s poster described computational work that is carried out in collaboration with former CDAC student Josh Townsend, now at Sandia National Laboratories.

Next year’s Symposium will be held on February 14-15, 2023 and is tentatively scheduled to be an in-person event at the Buffalo Thunder Hotel and Casino in Albuquerque, NM.

Posters presented at this year’s symposium by CDAC graduate students illustrate the wide range of scientific work in which they are engaged:

Charlie Zoller, University of Illinois – Chicago
Highly Accurate EoS of Statically Compressed H₂ – He Mixtures

Roma Ripani, University of Illinois – Chicago
Hydrazine at High Pressures

Allison Pease, Michigan State University
Deformation of Iron Nitrides

Alexander Mark, University of Illinois – Chicago
Structural Studies of Bismuth Based High Temperature Superconductors to Megabar Pressures

Chantelle Kiessner, University of Utah
Strain-Rate Dependence of Texture Evolution in Zircon

Jacob Minnette, University of Tennessee
Radiation Response of Carbide Fuel-Type Materials to SHI Irradiation Across Different Grain Sizes

Brian Blankenau, University of Illinois – Urbana-Champaign
Exploring Pressure and Temperature Induced Martensitic Phase Transformations in Ni₂Mn_2-xIn_x Alloys

Hannah Bausch, Northwestern University
Shock-Ramp Compression of (Mg,Fe)O on the Z Machine: Preliminary Theory and Application to Ultra-Low Velocity Zones Atop the Core-Mantle Boundary

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As the number of exoplanets discovered continues to increase,  the question of whether they are capable of supporting life has become one of the key scientific questions in Earth and planetary science research today. To understand the dynamics of planetary interiors that may be similar to that of Earth, an understanding of the melting behavior of iron at the pressures of “Super Earth” planetary bodies can provide crucial constraints on accretion, differentiation, and dynamics.

As part of the Discovery Science Program at the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory (LLNL), Staff Scientist Richard Kraus and CDAC Director Russell Hemley and have recently led a dynamic compression study in which iron was compressed to terapascal pressures, nearly three times that of Earth’s core, to simulate the conditions of Super Earth cores. As the world’s most powerful laser, NIF has the capability to produce conditions unreachable with static compression or with other types of dynamic compression techniques.

Simultaneous measurements of X-ray diffraction during compression reveal that, with decreasing entropy at a constant peak pressure (as would be the case for a planet during cooling), iron undergoes a transition from a completely liquid state, to a mixed hcp-liquid, and finally to solid hcp state. This sequence of phase transformations is observed up to 1000 GPa, or 1 Terapascal (TPa), and constrains the melting behavior of iron up to four times greater pressure than previous measurements.

This work has important implications for models of solidification of planetary cores (Fig. 1) and the formation and duration of planetary dynamos. In the latter case, observations from the current work lead to the assertion that super Earth-sized planets should have a longer period during which conditions favoring habitability are possible due to magnetic shielding of cosmic radiation.

Kraus, R. G., R. J. Hemley, et al., Measuring the melting curve of iron at super-Earth core conditions.  Science 375, 202-205 (2022).

For a commentary on this work from Jung-Fu Lin, a former CDAC Research Scientist and current Professor in the Department of Geological Sciences at the University of Texas at Austin, see his Perspective.

LLNL Press Release

UIC Press Release

Perspectives Article in Physics Today

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Superhydrides of main group or rare earth elements  have received a great deal of attention in recent years due to the prediction and observation of superconductivity at our near room temperature at pressures approaching two megabars (200 GPa). Compounds containing a large excess of hydrogen, such as LaH₁₀, are a realization of the prediction that a metal hydride could exert a chemical “pecompression” and promote metallization and perhaps also superconductivity at pressures below the that required for the transition of pure hydrogen to the monoatomic, metallic, superconducting state.

Such experiments are especially challenging due to the synthesis pressures required, which approach the pressures at which the onset of superconductivity is observed. In new theoretical/computational work, CDAC Director Russell Hemley (University of Illinois – Chicago) and CDAC collaborators at Carnegie-Mellon University propose a synthesis method for superhydrides that combines high pressure with an electrochemical potential provided by an electrode inside the pressure cell.  The electrode is designed to surpress the evolution of hydrogen and at the same time allow the loading of hydrogen by modulating the activity of mobile protons from the electrolyte.

As an example, the calculated activity required to synthesize palladium hydrides as a function of pressure is illustrated in a Pourbaix diagram (Fig. 1). Although current experimental work has shown that PdH₁₀ would be difficult if not impossible to synthesize even at multimegabar pressures with laser heating, the pressure-potential method suggests that modest pressures of about 0.1- 1.0 GPa would be needed to synthesize this material in an electrochemical environment. Through a judicious choice of electrolyte that could suppress the hydrogen evolution reaction further, PdH₁₀ could be stable at even lower pressures with a more negative electrode potential. This approach may be extended to other superhydride systems, such as La-H, Y-H and Mg-H.

Guan, P.-W., R. J. Hemley and V. Viswanathan, Combining pressure and electrochemistry to synthesize superhydrides.  Proceedings of the National Academy of Sciences USA, 118, e2110470118 (2021).

UIC Press Release

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A new paper from groups at UIC, Rochester, HPCAT and GSECARS  reports an x-ray diffraction study of the recently discovered carbonaceous sulfur hydride (C–S–H) room-temperature superconductor. The study indicates that the structure of the C-S-H superconductor is derived from the structures of previously established van der Waals compounds found in the H₂S–H₂ and CH₄–H₂ systems.

Crystals of the superconducting phase were produced by a photochemical synthesis technique, and yielded a superconducting critical temperature (T_c) of 288 K at 267 GPa. For this work, x-ray diffraction patterns measured from 124 to 178 GPa (i.e. within the pressure range of the superconducting phase), are consistent with an orthorhombic structure derived from the Al₂Cu-type determined for (H₂S)₂H₂ and (CH₄)₂H₂ but differ from those predicted and observed for the H₃S system, which also exhibits a very high T_c at these pressures.

The formation and stability of the C–S–H compound may be understood in terms of the close similarity in effective volumes of the H₂S and CH₄ components (Fig. 1) Denser carbon-bearing S–H phases are predicted to form at higher pressures, and the current results provide a critical starting point for understanding the very high superconducting transition temperatures found in the C–S–H system at megabar pressures.

Lamichhane, A., et al., X-ray diffraction and equation of state of the C–S–H room-temperature superconductor.  Journal of Chemical Physics 155, 114703 (2021).

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Apart from its fascinating crystal structures and their structural chemistry,  the high pressure behavior of boron is of critical importance in high-energy density research, particularly due to its role as an ablator in inertial confinement fusion experiments.

New theoretical and computational results from a collaboration led by CDAC Postdoctoral Associate Katerina Hilleke and CDAC Academic Partner Eva Zurek at the University at Buffalo, and including colleagues at Lawrence Livermore National Laboratory and the University of Rochester/Laboratory for Laser Energetics, sheds new light on the behavior of boron at megabar pressures, and provides structural models for understanding the stability of several predicted high-pressure polymorphs containing unique structural motifs.

Using evolutionary algorithm routines implemented in the XtalOpt code, the group predicts several metastable phases of boron that are dynamically stable at 100 GPa, and which can be sorted into two different types. One is based on the structure of α-Ga, and the other consists of channels along the c direction of a monoclinic lattice (Fig. 1). In addition, two intergrowth structures are predicted that are comprised of both a-Ga and channel-based structural units. These phases contain a combination of 2 center – 2 electron, 3 center – 2 electron and 4-center – 2 electron boding motifs, showing that not only are the complex structural features of α-B₁₂ retained at high pressures, but new motifs are generated.

Several of the structures predicted in this work are calculated to be metastable at ambient pressure. With Vickers hardnesses in the range of 36 GPa, these phases, if they could be synthesized by a high P-T route and quenched, have the potential to be useful in a variety of practical applications.

Hilleke, K. P., et al., Structural motifs and bonding in two families of boron structures predicted at megabar pressures. Physical Review Materials 5, 053605 (2021).

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A new CDAC paper from the groups at Buffalo, UIC, and LLNL  reports predictions of new pressure-induced chemistry between LiF and hydrogen, with results that have implications for dynamic compression experiments.

Lithium fluoride is a common window in shock compression experiments, and pressure-induced chemical reactions between hydrogen and LiF windows in dynamic compression experiments near 300 GPa, could affect the interpretation of the results. Given the propensity for formation of stable and metastable ternary hydrides under pressure, crystal structure prediction techniques were applied to study the Li-F-H system to multimegabar pressures. Phase diagrams of the elemental (Li, H, and F) and binary (Li-H, H-F, and Li-F,) systems have been studied computationally corresponding to pressures up to 300 GPa, and these results have provided a well-established starting point for exploration of potential high pressure phases in the ternary system.

Evolutionary crystal structure prediction techniques were used evaluate ground state structures containing the elements Li, F, and H at elevated pressures. None of the structures found suggest compound formation in NIF experiments from the combination of LiF and hydrogen isotopes. A number of intriguing metastable phases, however, are predicted that could potentially be synthesized. Common structural motifs present in these phases include H_nF_n+1^– anions of various lengths, and Li⁺ counter-cations. Most of these crystalline phases are predicted to be wide-gap insulators, with the exception of LiF₃H, which calculations predict to be metallic and superconducting below 0.1 K. Li₃F₄H is found to be thermodynamically and dynamically stable at atmospheric pressure.

Exploratory calculations on the Li₃F₄H composition predict a structure that contains bent and asymmetric bifluoride anions, as well as infinite HF chains with nearly equal bond lengths, whose enthalpy lies 21.7 meV/atom above the convex hull. The fact that Li₃F₄H is predicted to be thermodynamically and dynamically stable at ambient pressure, suggests that other Li-F-H compounds with unique H_nF_n+1-type compositions could also be synthesized and stabilized at ambient conditions (Fig. 1).

These studies provide the basis for future work exploring the finite temperature stability of Li-F-H phases, with the inclusion of anharmonic effects, which are known to be important for light element systems, especially at high pressures.

Bi, T. , A. Shamp, T. Terpstra. R. J. Hemley and E. Zurek, The Li-F-H ternary system at high pressures.  Journal of Chemical Physics 154, 124709 (2021).

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The 2021 Stewardship Science Academic Programs (SSAP) Symposium  was held in virtual mode from February 16th through the 18th. Principal Investigators for SSAP grants and centers provided updates on their activities through oral presentations, while students supported by SSAP grants and centers also presented their posters this year in five-minute video segments.

The Keynote Address for this year’s symposium was presented by Dr. Mark Anderson, who is the Assistant Deputy Administrator in the Office of Research, Development, Test and Evaluation at DOE/NNSA. Dr. Anderson outlined recent progress in the area of stewardship science, along with scientific and technical challenges that lie ahead, as well as plans for the future, particularly in the development of new experimental and computational capabilities.  He emphasized the wide and continuously growing range of opportunities available within the NNSA laboratory complex for scientists, engineers, and other technical professionals.

CDAC was once again well represented at the SSAP Symposium this year. Eleven posters were presented by Center graduate students and represented the Academic Partner groups as well as UIC:

Hannah Bausch (Northwestern) : Origin of the ultra-low velocity zones atop Earth’s core-mantle boundary: Shock-ramp compression of iron-rich (Mg,Fe)O

Brian Blankenau (Illinois/Urbana-Champaign) : First-principles description of the Martensitic phase transformation in Ni₂FeGa

Samantha Couper (Utah) : Variant selection across the cubic/monoclinic phase transition in wüstite

Zach Chaney (Tennessee) :  Effects on oxidation of zirconium carbide induced by dense electronic excitation

Adam Denchfield (Illinois/Chicago) : Role of zero-point motion in phase transitions of hydrides

John Hirtz (Tennessee) : Solids at extreme conditions: Coupling high pressure with ion beams

Chantelle Kiessner (Utah) : Investigating impacts with high pressure and temperature experiments

Mingda Lyu (Michigan State) : Spin transitions and compressibility of ε-Fe₇N₃ and γ’-Fe₄N: Implications for iron in terrestrial planet cores

Alexander Mark (Illinois/Chicago) : Compression of BSCCO to megabar pressures

Allison Pease (Michigan State) : Deformation of iron nitrides under uniaxial compression to 55 GPa

Charlie Zoller (Illinois/Chicago) : Static pressure-volume equation of state of helium-hydrogen mixtures

Presentations from this year’s symposium will be available on the 2021 SSAP Symposium website.  Next year’s SSAP Symposium is planned for February 2022 at the Buffalo Thunder Hotel in Santa Fe, NM.

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The expanding research field that is concerned with the a priori prediction and design of materials  has led to successful syntheses of phases that were first proposed in theoretical calculations, including the fascinating Fm-3m LaH₁₀ phase, which is consistent with a compound with measured T_c values up to 280 K at 200 GPa. With advances in materials synthesis, computational techniques such as the XtalOpt evolutionary algorithm,designed to predict novel and intriguing structures, have similarly become more adept.  New work in the group of CDAC Academic Partner Eva Zurek at the University at Buffalo has resulted in the implementation of new structure prediction tools in the XtalOpt evolutionary algorithm for crystal structure prediction. Forthcoming papers from the Zurek group detail the use of the XtalOpt methodology to determine stable structures at high pressure in the boron and Li-H-F systems.

XtalOpt starts with an initial set of randomly generated structures, which are encouraged towards local order using the newly implemented mitosis and randSpg techniques, respectively breaking down large unit cells into supercells of smaller identical components or enforcing user-defined space groups.  Increased local order speeds convergence towards low-enthalpy structures, while the search can be further tailored by the imposition of custom interatomic distance cutoffs and including molecular units in the initial geometries. A search can consider multiple formula units of a given stoichiometry at once, with the user choosing whether and when to allow crossovers between structures with different numbers of formula units. Duplicate structures are removed after detection with the XtalComp algorithm, which directly maps structures onto one another following reduction into a standard orientation.

Finally, stable and superhard materials can be directly targeted, with hardness values calculated by a machine learning model based on the Automatic FLOW (AFLOW) database, which is incorporated into a modified fitness function used to select structures for further procreation. Several new metastable and superhard allotropes of carbon have been identified using this method. All of the search options, along with the progress of the search, can be monitored on-the-fly via a GUI implementation, which shows lists of enthalpies and space groups as well as plots of enthalpy against the generations of structures.

Falls, Z. et al., The XtalOpt evolutionary algorithm for crystal structure prediction.  Journal of Physical Chemistry C 125, 1601-1620 (2021).

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The availability of synchrotron x-ray diffraction, x-ray spectroscopy and infrared spectroscopy  has enabled numerous advances in the physics of materials at extreme conditions, and the physics of materials with correlated electrons and their behavior at high pressure has been an ongoing area of emphasis.  Recently, the Jacobsen group at Northwestern used multiple synchrotron techniques in a study of the frustrated antiferromagnetic material jarosite, KFe₃(OH)₆(SO₄)₂.  The work combined results from x-ray diffraction and x-ray emission spectroscopy at the HPCAT sector at the Advanced Photon Source (APS), Argonne National Laboratory, synchrotron Mössbauer spectroscopy at APS Sector 3, and synchrotron IR spectroscopy at the Frontier Infrared Spectroscopy facility at NSLS-II, Brookhaven National Laboratory.  At approximately 45 GPa, the Kagomé net of Fe³⁺ centers undergoes a collapse of magnetic order, accommodated by the formation of an unusual twisted net in which the triangular geometry of the equilateral triangles of Fe³⁺ ions is preserved (Fig. 1).

Klein, R. A. et al., Collapse of magnetic order in jarosite. Physical Review Letters 125, 077202 (2020).

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The growth of single-crystal diamond by chemical vapor deposition (CVD)  has been a long-standing research direction within the CDAC scientific program. These studies have included the development of CVD chamber technologies as well as the optimization of diamond growth chemistry and the analysis of the enhanced strength and toughness of CVD diamond as compared the natural material. In a recent outgrowth of these studies, a collaboration between Penn State University and CDAC has resulted in the first silicon optical fibers encapsulated by diamond grown by CVD methods (Fig. 1). These fibers, which have a homogeneous diamond morphology over their entire length, have been shown to guide infrared light, and may provide significant enhancements in remote sensing and structural monitoring in extreme environments or when probing for chemical signatures at mid-infrared wavelengths.

Hendrickson, A.T. et al., Diamond Encapsulated Silicon Optical Fibers Synthesized by Chemical Vapor Deposition. AIP Advances 10, 095009 (2020).

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